Water-based paints contain potentially hazardous chemicals

Water-based paints are typically considered ‘greener’ and less smelly than solvent-based options, and they are often advertised as containing little-to-no volatile organic compounds (VOCs). But according to new research published in the journal Environmental Science & Technology Letters, some of these paints do contain compounds that are considered VOCs, along with other chemicals of emerging concern.

Paint consists of four ingredients: pigments, binders, additives and a liquid. If the liquid is water — as in latex and some acrylic paints — it’s classified as a water-based paint, rather than solvent-based. Historically, solvent-based paints were easy to apply and durable, though they released foul-smelling VOCs into the air both during and after application, stinking up a newly painted room. These airborne VOCs can cause respiratory irritation and headaches, among other potential health problems, especially in high concentrations or over long periods of time.

Tsinghua University’s Ying Xu and colleagues wanted to understand more about the formulations of water-based paints, which are often labelled as zero- or low-VOC (the team acknowledges that there are differing definitions of what constitutes a VOC, some of which are stricter than others). They collected 40 water-based paints from around the world, all ranked among the top 70 most-sold brands. Both dry and wet samples were analysed by gas chromatography–mass spectrometry to determine their composition.

The team identified 20 semi-volatile organic compounds in the tested samples, in concentrations ranging from 10 to 35,000 parts per million. While less likely to be in a gaseous form, these can still persist indoors for years, often incorporated into dust.

Endocrine-disrupting phthalates, which act as binders, were largely absent in the tested paints. However, several phthalate-replacement chemicals were detected — their toxicities are still being assessed. Furthermore, nearly half the analysed samples contained measurable amounts of isothiazolinones — preservatives that have been linked to skin irritation and asthmatic symptoms.

Finally, in 24 of the wet paint samples advertised as either zero- or low-VOC, 11 different VOCs were detected at concentrations up to 20,000 parts per million. The researchers noted that these concentrations represent the chemical composition within the paint, not the air, so further studies are required to understand how much of these potentially hazardous compounds become airborne as painted surfaces are drying. This work could allow for the design of safer paint products in the future.

Image credit: iStock.com/Bill Oxford