CO2 could be stored below the ocean floor

To combat the effects of climate change, scientists are searching for new technologies that could help the world reach carbon neutrality. One potential solution that is drawing growing attention is to capture and store carbon dioxide (CO₂) emissions in the form of hydrates under ocean floor sediments, kept in place by the natural pressure created by the weight of the sea water above.

A major issue here is how stable this stored CO₂ would be for the extended periods of storage required to keep the carbon in place and out of the atmosphere. Now researchers from National University of Singapore (NUS) have demonstrated experimental evidence of the stability of CO₂ hydrates in oceanic sediments — an essential step in making this carbon storage technology a viable reality.

Using a specially designed laboratory reactor, the NUS team showed that CO₂ hydrates can remain stable in oceanic sediments for a period of up to 30 days. Going forward, the researchers say, the same process can be used to validate the stability of CO₂ hydrates for much longer periods. Their findings have been published in the Chemical Engineering Journal.

At low temperature and under high-pressure conditions created by the ocean, CO₂ can be trapped within water molecules, forming an ice-like substance. These CO₂ hydrates form at a temperature just above the freezing point of water and can store as much as 184 m³ of CO₂ in 1 m³ of hydrates. The presence of huge volumes of methane hydrates in similar locations around the world and their safe existence presents a natural analogy to support the belief that CO₂ hydrates will remain stable and safe if stored in deep-oceanic sediments.

Working with specially designed equipment, Professor Praveen Linga and his team recreated the conditions of the deep ocean floor, where temperatures range between 2 and 6°C and pressures are 100 times higher than what we experience at sea level. Creating a macro-scale reactor that could maintain such conditions was challenging and is one of the reasons why experiments to test the stability of CO₂ hydrates were previously not possible. The NUS team overcame this challenge using an in-house designed pressurised vessel, lined with a silica sand bed, which imitated ocean sediments.

The team was able to form solid hydrates on top and within the silica sand bed and transitioned the pressurised vessel to mimic oceanic conditions to observe the stability of the formed solid CO₂ hydrates in sediments. Under pressurised conditions, the hydrates were observed for 14 to 30 days and were found to show a high degree of stability.

This hydrate technology would allow nations to sequester large volumes of carbon emissions in deep-ocean geological formations in addition to how it is currently stored in depleted oil and gas reserves and saline aquifer formations. For countries like Singapore, which has set a target to become carbon neutral by 2050, the technology could be a significant tool for reducing CO₂ emissions.

The next step for the team will be to scale up the experiment’s volume and timescale, with the aim of creating a commercial-scale process that allows Singapore to efficiently sequester more than two million tons of CO₂ annually to meet emission reduction targets.

“From an experimental standpoint, we are planning to scale up by 10 times along with further innovations to develop quantifiable tools and methods for the technology,” Prof Linga said.

Moving forward, he added, the team aims soon to demonstrate six months’ stability for the CO₂ hydrates. With the planned future experiments, the team hopes to develop and validate models that can predict the stability of CO₂ hydrates thousands of years into the future.

“In order to achieve carbon-neutrality targets, we have to look at new options that provide scale and speed to sequester CO₂,” Prof Linga said. “Deep-ocean sequestration in sediments as CO₂ hydrates is a promising solution.”

Image credit: ©stock.adobe.com/au/Richard Carey

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